ACETO ORCEIN MSDS

 

Product Name RXSOL-60-6507-001
Product Type ACETO ORCEIN
Revised date 27-04-2019

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka

Phone +91 22 27815541 / 42
Fax +91 22 2781 1318 :::AOH :0091 9821214367
Email mail@rxmarine.com

2.1. Substance: ACETO ORCEIN
Substance name Contents CAS No
Water 50 - 75 7732-18-5
Acetic acid 25 – 50 64-19-7
Orcein 0.01 - 1 1400-62-0
Substance.
Contains no other components or impurities which will influence the classification of the
product
3.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008
[CLP]Mixture/Substance: SDS EU 2015: According to Annex II
of Regulation (EC) No. 453/2010 (REACH Annex II)
Skin corrosion/irritation, H314
Category 1A
Full text of classification categories and H statements : see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
3.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to
displayExtra classification(s) to display
Symbol(s) : C: Corrosive
R Phrase(s):R36/38 Irritating to eyes and skin.
S Phrase(s) :S2: Keep out of reach of children.
S26: In the case of contact with eyes, rinse immediately with plenty of water and seek
medical advise.
Hazard pictograms:
Signal word: Danger
Hazard statements: H314 - Causes severe skin burns and eye damage
Precautionary statements: P280 - Wear protective gloves, protective clothing, eye
protection, face protection P305+P351+P338 - IF IN EYES: Rinse cautiously with water
for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately
call a doctor
3.3. Other hazards
No additional information available
4.1. Description of first aid measures
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a
position comfortable for breathing.
Immediately call a POISON CENTER or doctor/physician.
First-aid measures after skin contact : Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or
doctor/physician.
First-aid measures after eye contact : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a
POISON CENTER or doctor/physician.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately
call a POISON CENTER or doctor/physician.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : Causes severe skin burns and eye damage.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically. 
 

5.1. Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use extinguishing media containing water.
5.2. Special hazards arising from the substance or mixture
No additional information available
5.3. Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective
equipment, including respiratory protection.
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Use personal protective equipment as required.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : On land, sweep or shovel into suitable containers. Collect
spillage.
6.4. Reference to other sections
No additional information available
7.1. Precautions for safe handling
Precautions for safe handling : Do not breathe vapours. Avoid contact with skin and eyes.
Provide good ventilation in process area to prevent formation of vapour.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and
other exposed areas with mild soap and water before eating, drinking or smoking and
when leaving work.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3. Specific end use(s)
No additional information available
8.1. Control parameters
No additional information available
8.2. Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or face shield
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection
 
9.1. Information on basic physical and chemical properties
Odour threshold : 1.018 ppm
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 16.6 °C
Freezing point : No data available
Boiling point : 100 °C
Flash point : 39 °C
Auto-ignition temperature : 427 °C
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : 2.3 kPa at 20°C)
Relative vapour density at 20 °C : 2.07
Relative density : No data available
Density : 1.03 g/cm³
Solubility : Water: Soluble in water
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : 0.04 - 0.199 vol %
9.2. Other information
No additional information available.
10.1. Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No additional information available
10.4. Conditions to avoid
Direct sunlight. Overheating. Open flame. Heat. Sparks.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
Thermal decomposition generates : Corrosive vapours.
11.1. Information on toxicological effects
Acute toxicity : Not classified
Skin corrosion/irritation : Causes severe skin burns and eye damage.
Serious eye damage/irritation : Serious eye damage, category 1, implicit
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified

12.1. Toxicity
No additional information available
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
No additional information available

13.1. Waste treatment methods
General : Avoid release to the environment. Dispose in a safe manner in accordance with
local/national regulations.Dispose of this material and its container to hazardous or
special waste collection point, in accordance with local, regional, national and/or
international regulation.
Special precautions : Handle empty containers with care because residual vapours are
flammable.

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1760
UN-No. (IMDG) : 1760
UN-No.(IATA) : 1760
UN-No.(ADN) : 1760
UN-No. (RID) : 1760
14.2. UN proper shipping name
Proper Shipping Name (ADR) : CORROSIVE LIQUID, N.O.S.
Proper Shipping Name (IMDG) : CORROSIVE LIQUID, N.O.S.
Proper Shipping Name (IATA) : CORROSIVE LIQUID, N.O.S.
Proper Shipping Name (ADN) : CORROSIVE LIQUID, N.O.S.
Proper Shipping Name (RID) : CORROSIVE LIQUID, N.O.S.
Transport document description (ADR) : UN 1760 CORROSIVE LIQUID, N.O.S., 8, II,
(E)
Transport document description (IMDG) : UN 1760 CORROSIVE LIQUID, N.O.S., 8, II
Transport document description (IATA) : UN 1760 CORROSIVE LIQUID, N.O.S., 8, II
Transport document description (ADN) : UN 1760 CORROSIVE LIQUID, N.O.S., 8, II
Transport document description (RID) : UN 1760 CORROSIVE LIQUID, N.O.S., 8, II
14.3. Transport hazard class(es)
ADR : Transport hazard class(es) (ADR) : 8
Danger labels (ADR) : 8
IMDG : Transport hazard class(es) (IMDG) : 8
Danger labels (IMDG) : 8
IATA : Transport hazard class(es) (IATA) : 8
Hazard labels (IATA) : 8
AND : Transport hazard class(es) (ADN) : 8
Danger labels (ADN) : 8
RID : Transport hazard class(es) (RID) : 8
Danger labels (RID) : 8
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : C9
Special provision (ADR) : 274
Limited quantities (ADR) : 1L
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P001, IBC02
Mixed packing provisions (ADR) : MP15
Portable tank and bulk container
instructions (ADR) : T11
Portable tank and bulk container special
provisions (ADR) : TP2, TP27
Tank code (ADR) : L4BN
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Hazard identification number (Kemler No.) : 80
Orange plates : Tunnel restriction code (ADR) : E
EAC code : 2X
APP code : B
- Transport by sea
Special provision (IMDG) : 274
Limited quantities (IMDG) : 1 L
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P001
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T11
Tank special provisions (IMDG) : TP2, TP27
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-B
Stowage category (IMDG) : B
Stowage and handling (IMDG) : SW2
MFAG-No : 154
- Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y840
PCA limited quantity max net quantity
(IATA) : 0.5L
PCA packing instructions (IATA) : 851
PCA max net quantity (IATA) : 1L
CAO packing instructions (IATA) : 855
CAO max net quantity (IATA) : 30L
Special provision (IATA) : A3
ERG code (IATA) : 8L
- Inland waterway transport
Classification code (ADN) : C9
Special provisions (ADN) : 274
Limited quantities (ADN) : 1 L
Excepted quantities (ADN) : E2
Carriage permitted (ADN) : T
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : C9
Special provision (RID) : 274
Limited quantities (RID) : 1L
Excepted quantities (RID) : E2
Packing instructions (RID) : P001, IBC02
Mixed packing provisions (RID) : MP15
Portable tank and bulk container
instructions (RID) : T11
Portable tank and bulk container special
provisions (RID) : TP2, TP27
Tank codes for RID tanks (RID) : L4BN
Transport category (RID) : 2
Colis express (express parcels) (RID) : CE6
Hazard identification number (RID) : 80
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
PCA limited quantity max net quantity
(IATA) : 0.5L
PCA packing instructions (IATA) : 851
PCA max net quantity (IATA) : 1L
CAO packing instructions (IATA) : 855
CAO max net quantity (IATA) : 30L
Special provision (IATA) : A3
ERG code (IATA) : 8L
- Inland waterway transport
Classification code (ADN) : C9
Special provisions (ADN) : 274
Limited quantities (ADN) : 1 L
Excepted quantities (ADN) : E2
Carriage permitted (ADN) : T
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : C9
Special provision (RID) : 274
Limited quantities (RID) : 1L
Excepted quantities (RID) : E2
Packing instructions (RID) : P001, IBC02
Mixed packing provisions (RID) : MP15
Portable tank and bulk container
instructions (RID) : T11
Portable tank and bulk container special
provisions (RID) : TP2, TP27
Tank codes for RID tanks (RID) : L4BN
Transport category (RID) : 2
Colis express (express parcels) (RID) : CE6
Hazard identification number (RID) : 80
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
 
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
15.1.1. EU-Regulations
Contains no substances with Annex XVII restrictions
Contains no REACH candidate substance
Contains no REACH Annex XIV substances.
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to
water (Classification according to AwSV, Annex 1)
12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not
subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Class for fire hazard : Class II-1
Store unit : 5 liter
Classification remarks : R10 <H314>; Emergency management guidelines for the storage
of flammable liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not
allowed to use the product
15.2. Chemical safety assessment
No additional information available
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Product: 
ACETO ORCEIN
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